Using PO_DT field in Oracle, Trying to get the First Date of week based on value of PO_DT.
You can truncate a date column to the week, eg
SQL> alter session set nls_date_format = 'DAY DD-MON-YYYY';
Session altered.
SQL> select trunc(sysdate,'IW') from dual;
TRUNC(SYSDATE,'IW')
---------------------
MONDAY 03-APR-2017
Note that depending on your country/territory settings the "first" day of the week might not be deemed to be a Monday, so double check that as well.